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Robert Pollice

robpollice@mstdn.science

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Weekly #RobSelects Assistant Professor for Computer-Aided Organic Synthesis at the Stratingh Institute for Chemistry, University of Groningen (he/him/his)

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Joined November 2024

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Robert Pollice robpollice@mstdn.science · May 19, 2025
#RobSelects preprint of the week #ChemRxiv: Nitrogen-nitrogen dehydrocoupling of iminoanilines via iron(III) chloride-catalyzed multi-site proton-coupled electron transfer. #catalyis doi.org/10.26434/chemrxiv-2…
N-N Bond Formation Through N-H Dehydrocoupling

N-N bond formation from amines can be accomplished through proton/electron transfer using simple base and oxidant combinations, where kinetic limitations related to the BDFE(eff) of a particular base/oxidant pair can be overcome using Lewis acid catalysts such as FeCl3.

chemrxiv.org

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